109619-17-2Relevant academic research and scientific papers
REACTIONS OF 3-ARYL-1--2-PROPYN-1-ONES IN THE PRESENCE OF AMINES. TWO TYPES OF INTRAMOLECULAR CYCLIZATION INVOLVING THE ortho-HYDROXYL GROUP
Korshunov, S. P.,Korzhova, N. V.,Kazantseva, V. M.,Krasnov, V. L.,Utekhina, N. V.,Bodrikov, I. V.
, p. 1658 - 1663 (2007/10/02)
Amines react with 3-aryl-1--2-propyn-1-ones in three directions, i.e., with addition of the reagent at the triple bond (and the formation of the β-aminovinyl ketone) and intramolecular cyclization leading to the formation of six-membered (flavones) or five-membered (aurones) heterocycles.The development of these reaction paths is controlled by the nature of the amines.Probable reaction paths are proposed.
