1096445-96-3Relevant academic research and scientific papers
A truly multifunctional heterocycle: Iminophosphorane, N,P chelate, and dihydropyridine
Smith, Dan A.,Batsanov, Andrei S.,Miqueu, Karinne,Sotiropoulos, Jean-Marc,Apperley, David C.,Howard, Judith A. K.,Dyer, Philip W.
, p. 8674 - 8677 (2008)
(Chemical Equation Presented) Three in one: The anellated σ4-1λ5-[1,3,2]diazaphosphole 2 exists in tautomeric equilibrium with isomer 1 (see scheme) and undergoes three completely different types of reaction: trimethyl aluminum binds at the N terminus of the P=N bond with ring retention, the dihydropyridine fragment reacts with an activated acetylene in a pseudo-[2+2] cycloaddition, and P-N bond cleavage is possible with RhI.
