1096491-30-3Relevant academic research and scientific papers
A quantitative structure-reactivity relationship in decarboxylative Claisen rearrangement reactions of allylic tosylmalonate esters
Craig, Donald,Slavov, Nikolay K.
supporting information; experimental part, p. 6054 - 6056 (2009/05/06)
First-order rate constants have been determined for the decarboxylative Claisen rearrangement reactions at 293 K of substituted methyl (E)-3-phenyl-2-propenyl 2-tosylmalonate esters, which show a linear free-energy relationship indicative of the development of positive charge on the benzylic position in the sigmatropic rearrangement transition-state. The Royal Society of Chemistry.
