109669-31-0Relevant academic research and scientific papers
Biradical Reversion in the Intramolecular Photochemistry of Carbonyl-Substituted 1,5-Hexadienes
Schroeder, Clemens,Wolff, Steven,Agosta, William C.
, p. 5491 - 5497 (2007/10/02)
We have studied the intramolecular photochemistry of dienones 10a,b-12a,b.The initial rate of loss of alkene stereochemistry in recovered starting ketone provides a measure of the rate of reversion (kr) of the biradical intermediate (SchemeI) r
