1097140-08-3Relevant academic research and scientific papers
Intermolecular N-heterocyclic carbene catalyzed hydroacylation of arynes
Biju, Akkattu T.,Glorius, Frank
, p. 9761 - 9764 (2010)
A formal introduction: The conceptually new N-heterocyclic carbene catalyzed formal insertion of arynes into the Cformyl-H bond of aldehydes demonstrates the compatibility of nucleophilic NHCs with electrophilic arynes. This NHC-catalyzed hydroacylation of arynes allows the conversion of aliphatic, α,β-unsaturated, and aromatic aldehydes into aryl ketones; 27 examples and a preliminary mechanistic investigation are provided. Copyright
