1097189-55-3Relevant academic research and scientific papers
Towards bis(acylsilanes) and cyclic unsaturated acylsilanes via metathesis: an exploratory study
Hammaecher, Catherine,Bouillon, Jean-Philippe,Portella, Charles
experimental part, p. 5527 - 5534 (2009/12/03)
New acyl(allyl)- and acyl(vinyl)silanes have been synthesized in order to explore cross metathesis or ring-closing metathesis as a new way towards bis(acyl)silanes or unsaturated cyclic acylsilanes, respectively. Metathesis from acylsilanes did not work b
New 6-oxa-2-silabicyclo[2.2.0]hexanes by photochemical conversion of acyl(allyl)(dimethyl)silanes
Hammaecher, Catherine,Portella, Charles
supporting information; scheme or table, p. 5833 - 5835 (2009/04/13)
Under UV irradiation in acetonitrile, acyl(allyl)silanes undergo an intramolecular (2+2) cycloaddition (Paterno-Buechi type reaction) to give unprecedented 1-alkyl-6-oxa-2-silabicyclo[2.2.0] hexanes. The Royal Society of Chemistry.
