109749-99-7Relevant academic research and scientific papers
Electron-transfer Platinum Complexes of Esters of Dithiocarbazic Acid. The Crystal and Molecular Structure of
Fares Vincenzo,Giuliani, Anna Maria,Imperatori, Patrizia,Suber, Lorenza,Tarli, Franco
, p. 1035 - 1040 (2007/10/02)
The ligand behaviour of the esters of dithiocarbazic acid NHRNHC(=S)SR' in intensely coloured complexes containing the doubly deprotonated ligands (R = H, R' = CH2Ph; R = CH2Ph, R' = Me or CH2Ph; R = Pri, R' = Me; R = hexyl, R'= Me or CH2Ph) has been investigated by electronic, i.r., and 1H n.m.r. spectroscopy and electrochemistry.The crystal and molecular structure of has also been determined.All the complexes have a square-planar trans-PtN2S2 chromophore; they are dithiolene-like and show electron-transfer properties.
