1097736-12-3Relevant articles and documents
Rhodium-catalysed hydroacylation or reductive aldol reactions: A ligand dependent switch of reactivity
Osborne, James D.,Willis, Michael C.
supporting information; experimental part, p. 5025 - 5027 (2009/06/05)
The pathway for the combination of enones and β-S-substituted aldehydes using Rh-catalysis can be switched between a hydroacylation reaction or a reductive aldol reaction by simple choice of the phosphine ligand; this catalyst controlled switch allows access to new ketone hydroacylation products; useful 1,4-diketone intermediates for the synthesis of N-, S- and O-heterocycles. The Royal Society of Chemistry.