1097835-27-2Relevant academic research and scientific papers
Formation of boronate ester polymers with efficient intrastrand charge-transfer transitions by three-component reactions
Christinat, Nicolas,Croisier, Emmanuel,Scopelliti, Rosario,Cascella, Michele,Roethlisberger, Ursula,Severin, Kay
, p. 5177 - 5181 (2007)
The three-component reaction of aryl boronic acids with 1,2,4,5-tetrahydroxybenzene and 1,2-bis(4-pyridyl)ethylene or 4,4′-bipyridine leads to the formation of dark-purple boronate ester polymers. Crystallographic analyses show that the polymer strands have a zig-zag geometry, and the bis(dioxaborole) units are connected by dipyridyl linkers through dative B-N interactions. Upon dissolution of the polymers in hot chloroform, most of the B-N connections are broken, which indicates that polymer formation is a reversible process. A computational study provides evidence that the strong color of the polymers is due to efficient intrastrand charge-transfer excitations from the tetraoxobenzene to the dipyridyl linker. Wiley-VCH Verlag GmbH & Co. KGaA, 2007.
