1097939-27-9

Upstream product

• 104-88-1 4-chlorobenzaldehyde 
• 77295-59-1 1-chloro-4-(2,2-dibromovinyl)benzene 
• 563-79-1 2,3-Dimethyl-2-butene 
• 66482-29-9 1-[(E)-2-bromoethenyl]-4-chlorobenzene 
• 1073-67-2 4-vinylbenzyl chloride 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 

Relevant academic research and scientific papers

Direct Cross-Coupling of Allylic C(sp3)?H Bonds with Aryl- and Vinylbromides by Combined Nickel and Visible-Light Catalysis

An efficient protocol for the direct allylic C(sp3)?H bond activation of unactivated tri- and tetrasubstituted alkenes and their functionalization with aryl- and vinylbromides by nickel and visible-light photocatalysis has been developed. The method allows C(sp2)?C(sp3) formation under mild reaction conditions with good functional-group tolerance and excellent regioselectivity.

Iron-catalyzed 1,4-addition of α-olefins to dienes

Stereo-and Regiosetective 1,4-Addition A new intermolecular, stereo- and regioselective iron-catalyzed 1,4-addition of α-olefins to 1,3-dlenes using as low as 1 mol % of an iminopyridine-ferrous chloride complex was developed. Importantly, both double bon