109802-95-1Relevant academic research and scientific papers
Scope and limitations in the Jacobsen epoxidation of dienyl sulfones
Hentemann,Fuchs
, p. 5615 - 5618 (2007/10/03)
Symchiral (salen)Mn(III)CI complexes catalyze the epoxidation of 2-sulfonyl, 1,3 cyclic dienes with exceptional enantioselectivity. The incorporation of the sulfone moiety increases the enantioselectivity by up to 30%, relative to the unsubstituted cyclic
DIMERIZATION OF (E)-2-BENZENESULFONYL-1,3-ALKADIENES. THE BENZENESULFONYL GROUP EXERTS ACYCLIC STEREOCONTROL
Hoffmann, H. Martin R.,Weichert, Andreas,Slawin, Alexandra M. Z.,Williams, D. J.
, p. 5591 - 5602 (2007/10/02)
Mild dehydration of 2-benzenesulfonyl allylic alcohols 8 afforded a series of (E)-2-benzenesulfonyl-1,3-alkadienes 1 which dimerized to functionalized vinylcyclohexenes 3 in regio- and stereodefined manner.The configuration at C-3 in 3e was determined by
