109853-24-9Relevant academic research and scientific papers
PHOTOOXYGENATION OF PTERIDIN-2,4,7-TRIONES
Nishio, Takehiko,Nishiyama, Tadashi,Omote, Yoshimori
, p. 2979 - 2990 (2007/10/02)
The pteridin-2,4,7-trione 6,8'-endoperoxides are synthesized and their thermal reactions are examined.The pteridin-2,4,7-triones (1) reacted smoothly with singlet oxygen to yield the pteridin-2,4,7-trione 6,8'-endoperoxides (2-5).On warming the endoperoxide (2a) reverted to the starting pteridin-2,4,7-trione (1a) with liberation of singlet oxygen, which was confirmed by trapping experiment using typical singlet oxygen acceptors (7-12).
NEW AND STABLE ENDOPEROXIDE FROM THE PTERIDIN-2,4,7-TRIONE AND SINGLET OXYGEN
Nishio, Takehiko,Nishiyama, Tadashi,Omote, Yoshimori
, p. 5637 - 5640 (2007/10/02)
1,3,8-Trimethyl-6-phenylpteridin-2,4,7-trione (1) reacted with singlet oxygen to give the pteridin-2,4,7-trione 6,8'-endoperoxide (2), which on warming generates singlet oxygen.Generation of singlet oxygen from thermolysis of the endoperoxide (2) was confirmed by trapping experiments using typical singlet oxygen acceptors.
