109874-39-7Relevant academic research and scientific papers
Reactions of Halogen (2,4,6-tri-tert-butylphenylimino)phosphine Complexes with Electrophiles and Nucleophiles: Abstraction or Substitution of the Halogen
Niecke, E.,Nixon, J. F.,Wenderoth, P.,Passos, B. F. Trigo,Nieger, M.
, p. 846 - 848 (2007/10/02)
The structure of the first nickel halogeniminophosphine complex, i.e. (PEt3)2Ni(X-P=NAr)2 (Ar = 2,4,6-tri-tert-butylphenyl); X = Cl is reported; reactions of this and related compounds with AlCl3 afford the cationic complexes 7-10; the alkyliminophosphine complexes 12 and 13 are obtained by treatment of the chloroiminophosphine complexes 1a and 4a with Grignard reagent.
