109885-20-3Relevant academic research and scientific papers
Molybdenum Complexes of Some N-S Donors: Part I - Syntheses and Reactivity of Mo(VI) Complexes of Some Ring-substituted 4-Phenylthiosemicarbazides
Ghosh, Saktiprosad,Purohit, Sanchita
, p. 131 - 134 (2007/10/02)
A number of Mo(VI) complexes with ring-substituted 4-phenylthiosemicarbazides (LH) have been synthesized and characterised.These compounds are either six-coordinated cis-dioxo, or seven-coordinated species.In all the complexes the thiosemicarbazides are ligated to the Mo(VI) acceptor centre in the deprotonated enol form.All the compounds have been characterised by elemental analyses, spectral (UV-vis, IR), magnetic susceptibility and conductance studies.Change in the Mo=O stretching frequency as a function of the donor atom situated trans to the Mo=O bond and its implication for the probable structure of the complexes have also been discussed.Reactions of with monodentate nucleophiles like pyridine, imidazole and acetate have been examined.
