109925-96-4

Basic information

• Product Name: 6-Methyl-3-phenyl-6-trimethylsilanyloxy-5,6-dihydro-4H-[1,2]oxazine
• Synonyms: 6-Methyl-3-phenyl-6-trimethylsilanyloxy-5,6-dihydro-4H-[1,2]oxazine
• CAS NO: 109925-96-4
• Molecular Weight: 263.412
• Mol File: 109925-96-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6-Methyl-3-phenyl-6-trimethylsilanyloxy-5,6-dihydro-4H-[1,2]oxazine(CAS DataBase Reference)
• NIST Chemistry Reference: 6-Methyl-3-phenyl-6-trimethylsilanyloxy-5,6-dihydro-4H-[1,2]oxazine(109925-96-4)
• EPA Substance Registry System: 6-Methyl-3-phenyl-6-trimethylsilanyloxy-5,6-dihydro-4H-[1,2]oxazine(109925-96-4)

Safety Data

• Hazardous Substances Data: 109925-96-4(Hazardous Substances Data)

Upstream product

• 1833-53-0 2-(Trimethylsilyloxy)propene 
• 21572-32-7 2-chloro-1-phenyl-ethanone oxime 

Downstream Products

• 3042-21-5 2-methyl-5-phenyl-1H-pyrrole 

Relevant articles and documents

Efficient Synthesis of 6-Trimethylsiloxy- and 6-(Trimethylsilyl)methyl-3-phenyl-5,6-dihydroxy-4H-1,2-oxazines by Cycloaddition of α-Nitrosostyrene to Silyl Enol Ethers and Allyltrimethylsilane

The title compounds 3 are prepared in good yield from silyl enol ether 1 and α-nitrosostyrene 2, generated in situ from α-chloroacetophenone oxime 4.Allyltrimethylsilane smoothly affords cycloadduct 5 which could be opened to the unsturated ketone 6 or am