1099596-62-9Relevant academic research and scientific papers
Sequential energy and electron transfer in an artificial reaction center: Formation of a long-lived charge-separated state
Luo,Guldi,Imahori,Tamaki,Sakata
, p. 6535 - 6551 (2000)
A novel molecular triad, representing an artificial reaction center, was synthesized via linking a fullerene moiety to an array of two porphyrins (i.e., a zinc tetraphenyl porphyrin (ZnP) and a free base tetraphenyl porphyrin (H2P)). In this Zn
Porphyrin-naphthodiimide interactions as a structural motif in foldamers and supramolecular assemblies
Merican, Zulkifli,Johnstone, Ken D.,Gunter, Maxwell J.
, p. 2534 - 2543 (2009/02/02)
π-π Stacking interactions between electron deficient naphthalenediimides (NDI) and electron-rich porphyrins (POR) leading to charge transfer are shown to be prevalent in linked NDI-POR and POR-NDI-POR structures. For flexibly-linked systems, intramolecular interactions lead to S-shaped foldamers in solution, whereas intermolecular association is predominant in more rigid systems. The foldamer structures can be interrupted by competing aromatic solvents, by six-coordination of metallated porphyrin derivatives, by protonation of the free base porphyrin in non-metallated structures, and in facially sterically hindered porphyrins. The Royal Society of Chemistry 2008.
