1099651-68-9Relevant academic research and scientific papers
Mo(CO)6-mediated intramolecular pauson-Khand reaction of substituted Diethyl 3-Allyloxy-1-Propynylphosphonates
Moradov, Dorit,Quntar, Abed Al Aziz Al,Youssef, Manar,Smoum, Reem,Rubinstein, Abraham,Srebnik, Morris
, p. 1029 - 1033 (2009)
Cyclisation of diethyl 3-allyloxy-1-propynylphosphonates with Mo(CO) 6 under PK conditions to give 3-substituted-5-oxo-3,5,6,6a- tetrahydro-1H-cyclopenta[c]furan-4-ylphosphonate, 2a-h,in45-88% isolated yields was done. The R groups are always syn with Hb (where applicable). The stereochemistry was determined via both NMR and crystal X-ray analysis.
