1099751-82-2Relevant academic research and scientific papers
Highly regioselective allylic substitution reactions catalyzed by an air-stable (π-Allyl)iridium complex derived from dinaphthocyclooctatetraene and a phosphoramidite ligand
Ye, Ke-Yin,Zhao, Zhuo-An,Lai, Zeng-Wei,Dai, Li-Xin,You, Shu-Li
, p. 2109 - 2114 (2013/08/23)
An air-stable (π-allyl)iridium complex derived from dinaphthocyclooctatetraene and a phosphoramidite ligand has been synthesized and found to be highly efficient in iridium-catalyzed allylic substitution reactions. This catalyst features excellent regiose
Enantioselective iridium-catalyzed allylic aminations of allylic carbonates with functionalized side chains. Asymmetric total synthesis of (S)-vigabatrin
Gnamm, Christian,Franck, Geraldine,Miller, Nicole,Stork, Timon,Broedner, Kerstin,Helmchen, Guenter
experimental part, p. 3331 - 3350 (2009/05/27)
Indium-catalyzed aminations of allylic carbonates containing a variety of O-functional groups have been explored. High degrees of regio- as well as enantioselectivity were achieved with diacylamides under salt-free conditions and with arylamines. The results allowed the antiepilepsy drug (5)-vigabatrin to be prepared via a very short route.
