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New Terpenic Synthons: Methyl α- and γ-Dithiocyclogeranates
Gosselin, Pascal
, p. 267 - 270 (1987)
Methyl γ-dithiocyclogeranate, a new terpenic dithioester, was easily synthesized by the -sigmatropic rearrangement of tosylhydrazone derivative 6a.Treatment with acid gives methyl α-dithiocyclogeranate.Three methoxylated analogues are obtained in the
