11005-98-4

Upstream product

• 103813-95-2 C₆₀H₇₇N₃O₁₃ 
• 101703-47-3 5-O-(6-O-benzyl-2,3,4-tris-O-trimethylsilyl-β-D-mannopyranosyl)-1-N,6-O:3-N,4-O-dicarbonyl-1,3-di-N-methyl-2-deoxystreptemine 
• 103832-96-8 6-deoxy-6-ethoxycarbonylamino-2,3,4,7-tetra-O-(p-methylbenzyl)-L-glycero-D-galacto-heptono-1,5-lactone 
• 103813-96-3 5-O-<6-O-benzyl-2,3-O-<6-deoxy-6-ethoxycarbonylamino-2,3,4,7-tetra-O-(p-methylbenzyl)-L-glycero-D-galacto-(R)-heptopyranosylidene>-β-D-mannopyranosyl>-1-N,6O:3-N,4-O-dicarbonyl-1,3-di-N-methyl-2-deoxystreptamine 
• 103813-96-3 5-O-<6-O-benzyl-2,3-O-<6-deoxy-6-ethoxycarbonylamino-2,3,4,7-tetra-O-(p-methylbenzyl)-L-glycero-D-galacto-(R)-heptopyranosylidene>-β-D-talopyranosyl>-1-N,6-O:3-N,4-O-dicarbonyl-1,3-di-N-methyl-2-deoxystreptamine 
• 103813-97-4 C₆₈H₈₅N₃O₁₇Si 
• 6216-32-6 1,3-Bis-N-(benzyloxycarbonyl)-2-desoxystreptamin 
• 101703-44-0 2,3,4-Tri-O-allyl-6-O-benzyl-α-D-mannopyranosyl chloride 
• 101703-45-1 1,3-di-N-benzyloxycarbonyl-5-O-(2,3,4-tri-O-allyl-6-O-benzyl-β-D-mannopyranosyl)-2-deoxystreptamine 
• 103813-98-5 (3aR,4aS,7aR,8R,8aS)-8-((2S,3S,4S,5S,6R)-6-Benzyloxymethyl-3,4,5-trihydroxy-tetrahydro-pyran-2-yloxy)-3,5-dimethyl-hexahydro-benzo[1,2-d;5,4-d']bisoxazole-2,6-dione 
• 101703-46-2 1-N,6-O:3-N,4-O-dicarbonyl-1,3-di-N-methyl-5-O-(2,3,4-tri-O-allyl-6-O-benzyl-β-D-mannopyranosyl)-2-deoxystreptamine 
• 101703-40-6 methyl 2,3,4-tri-O-allyl-α-D-mannopyranoside 
• 101703-41-7 methyl 2,3,4-tri-O-allyl-6-O-benzyl-α-D-mannopyranoside 
• 101703-42-8 1-O-acetyl-2,3,4-tri-O-allyl-6-O-benzyl-α-D-mannopyranoside 

Relevant academic research and scientific papers

THE SYNTHESIS OF DESTOMYCIN C, A TYPICAL PSEUDO-TRISACCHARIDE OF DESTOMYCIN-GROUP ANTIBIOTICS

A synthesis is described of the pseudo-trisaccharide antibiotic, destomycin C, which contains orthoester and β-D-talopyranosidic linkages.A β-D-mannopyranosidic linkage was formed first in the presence of silver triflate in tetrahydrofuran.Glycosylidenati

SYNTHESIS OF DESTOMYCIN C, A PSEUDO-TRISACCHARIDE ANTIBIOTIC HAVING AN INTERGLYCOSIDIC SPIRO-ORTHOESTER LINKAGE

Destomycin C, a pseudo-trisaccharide antibiotic of orthosomycin family was synthesized via spiro-orthoester formation between 5-O-(β-D-mannopyranosyl)-2-deoxystreptamine and 6-amino-6-deoxyheptonolactone derivatives.