110087-11-1

Basic information

• Product Name: Tricyclo[4.1.0.02,7]heptan-3-one, 6-(1-methylethyl)- (9CI)
• Synonyms: Tricyclo[4.1.0.02,7]heptan-3-one, 6-(1-methylethyl)- (9CI)
• CAS NO: 110087-11-1
• Molecular Formula: C10H14O
• Molecular Weight: 150.21756
• Product Categories: ISOPROPYL
• Mol File: 110087-11-1.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 219.9±8.0 °C(Predicted)
• Appearance: /
• Density: 1.159±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Tricyclo[4.1.0.02,7]heptan-3-one, 6-(1-methylethyl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Tricyclo[4.1.0.02,7]heptan-3-one, 6-(1-methylethyl)- (9CI)(110087-11-1)
• EPA Substance Registry System: Tricyclo[4.1.0.02,7]heptan-3-one, 6-(1-methylethyl)- (9CI)(110087-11-1)

Safety Data

• Hazardous Substances Data: 110087-11-1(Hazardous Substances Data)

Upstream product

• 1619-28-9 3-isopropyl-cyclopent-2-enone 
• 74-86-2 acetylene 

Downstream Products

• 13656-81-0 nezukone 

Relevant articles and documents

A Photochemical route to 4-Alkyltropones including Nezukone

An acetonitrile solution of acetylene and 3-methylcyclopent-2-enone (4) was irradiated with Pyrex-filtered light from a mercury lamp to give 5-methylbicyclohept-6-en-2-one (6) and 6-methyl-tricyclo2,7>heptan-3-one (8).These were easily separated and when heated under reflux in ButOH with SeO2 gave the 4-methyltropone valence-tautomer 5-methylbicyclohept-3,6-dien-2-one (10) and 4-methyltropone (12), respectively, the latter in 20percent overall, unoptimized yield.Similar reactions with 3-isopropylcyclopent-2-enone (5) in the place of (4) led to the natural troponoid 4-isoproyltropone (nezukone) (13).