1100884-78-3Relevant articles and documents
Gem-Bromochlorospiropentane reactivity toward methyllithium: An unusual carbenoid rearrangement
Sedenkova, Kseniya N.,Averina, Elena B.,Grishin, Yuri K.,Kuznetzova, Tamara S.,Zefirov, Nikolai S.
experimental part, p. 8089 - 8094 (2010/10/19)
A skeletal carbenoid rearrangement of the gem-bromochlorospiropentanes in the presence of methyllithium has been studied. The synthetic and mechanistic aspects of this rearrangement as well as the influence of the halogen atom nature on the reaction pathway are discussed.
Carbenoid rearrangement in the series of substituted gem- dibromospiropentanes
Sedenkova,Averina,Grishin,Kuznetsova,Zefirov
experimental part, p. 950 - 957 (2009/06/18)
A series of new substituted gem-dibromospiropentanes was studied in a reaction with methyllithium at -55...-50°C. This reaction is a carbenoid rearrangement that leads to the formation of monomeric and dimeric bromocyclobutenes and also to the products of