1101207-02-6Relevant articles and documents
A versatile radical based approach to O-alkylated hydroxylamines and oximes
Quiclet-Sire, Béatrice,Woollaston, Daniel,Zard, Samir Z.
experimental part, p. 11917 - 11924 (2009/04/06)
O-Alkylhydroxylamines, often used for the preparation of bioconjugates, can be readily obtained by radical addition to suitable O-alkenylhydroxylamine derivatives. In the case of N-Boc-O-allylhydroxylamine, the addition is unexpectedly followed by elimination resulting in an overall allylation of the radical species.