1101249-66-4Relevant academic research and scientific papers
Remote stereocontrol mediated by a sulfinyl group: Synthesis of allylic alcohols via chemoselective and diastereoselective reduction of γ-methylene δ-ketosulfoxides
Ruano, Jose L. Garcia,Fernandez-Ibanez, M. Angeles,Fernandez-Salas, Jose A.,Maestro, M. Carmen,Marquez-Lopez, Pablo,Rodriguez-Fernandez, M. Mercedes
supporting information; experimental part, p. 1200 - 1204 (2009/07/18)
The efficiency of the sulfinyl group as a remote controller of the chemoselectivity and diastereoselectivity of the reduction of α,β-unsaturated α-[2-(p-tolylsulfinyl)phenyl] substituted ketones 1 has been demonstrated in reactions carried out under NaBH
