110163-98-9Relevant academic research and scientific papers
Preparation of new dialkyl benzene-, biphenyl-, and naphthalene- bis(α-oxoethanedithioates)
Voss, Jurgen,Sarafidis, Abraam,Sawluk, Andrzej,Schmidt, Gunther,Adiwidjaja, Gunadi
experimental part, p. 2249 - 2276 (2011/01/12)
Novel arene-bis- and -tris(-oxoethanedithioate) esters of the benzene, the biphenyl, and, in particular, the naphthalene series were prepared by reaction of the corresponding diazoacetyl or bromoacetyl derivatives with elemental sulfur in the presence of triethylamine in dry DMF, and subsequent direct alkylation of the produced dithiocarboxylate anions. The thiolation reaction of the diazoketones was significantly promoted by the addition of anhydrous calcium chloride (calcium chloride-activated thiolation, or CAT). Certain carbonyl-activated methylene and methyl compounds exhibiting no bromo or diazo substituents could be also transformed into dithioesters by the CAT reaction. The structure of three dithioesters was corroborated by X-ray structural analyses. Copyright Taylor & Francis Group, LLC.
THIOLATION WITH DIALKOXY DISULFANES - A NEW METHOD FOR THE PREPARATION OF DITHIOESTERS
Hoepping, Alexander,Mayer, Roland
, p. 389 - 392 (2007/10/02)
CH-acidic methyl groups can easily be converted into dithioesters by use of sulfur transfer reagents possessing a S2-unit and two leaving groups.A possible mechanism is discussed.
Activated Thiocarboxylic Esters; 8. Preparation of 2-Oxidithiocarboxylic Esters from Diazoketones
Sawluk, Andrzej,Voss, Juergen
, p. 968 - 970 (2007/10/02)
Reaction of diazoketones, which are easily available from acid chlorides, with elemental sulfur in the presence of triethylamine, followed by alkylation yields alkyl 2-oxodithiocarboxylates.
