110174-58-8Relevant articles and documents
Dicarbonyltris(η2-trans-cyclooctene)ruthenium: Synthesis and molecular structure of the first stable M(CO)2(olefin)3 type compound
Ball, Richard G.,Kiel, Gong-Yu,Takats, Josef,Krüger, Carl,Raabe,Grevels, Friedrich-Wilhelm,Moser, Rainer
, p. 2260 - 2261 (2008/10/08)
Photolysis of Ru(CO)5 or Ru3(CO)12 in the presence of trans-cyclooctene (t-COE) gives Ru(CO)5-x-(t-COE)x (x = 1-3). The bis- and tris(olefin) derivatives are obtained as a mixture of two isomers, symmetry D3 and C2. The structure of Ru(CO)2(t-COE)3 (D3 isomer) has been determined by X-ray diffraction.
