1101876-22-5Relevant academic research and scientific papers
From silphinenes to penifulvins: A biomimetic approach to penifulvins B and C
Gaich, Tanja,Mulzer, Johann
supporting information; experimental part, p. 272 - 275 (2010/03/25)
(Figure presented) The biomimetic total synthesis of penifulvins B and C uses a mefa-photocycloaddition as a key step which gives rapid access to the fenestranetype carboskeleton with control of an onring quaternary stereocenter. The route Is concise, stereocontrolled, scaleable, and flexibile and requires only one protecting group.
