110211-34-2Relevant academic research and scientific papers
Mild and phosphine-free iron-catalyzed cross-coupling of nonactivated secondary alkyl halides with alkynyl grignard reagents
Cheung, Chi Wai,Ren, Peng,Hu, Xile
supporting information, p. 2566 - 2569 (2014/05/20)
A simple protocol for iron-catalyzed cross-coupling of nonactivated secondary alkyl bromides and iodides with alkynyl Grignard reagents at room temperature has been developed. A wide range of secondary alkyl halides and terminal alkynes are tolerated to a
PALLADIUM-CATALYZED REDUCTION OF PROPARGYLIC ACETATES WITH SmI2. A MILD AND CONVENIENT METHOD FOR THE PREPARATION OF ALLENES
Tabuchi, Takanori,Inanaga, Junji,Yamaguchi, Masaru
, p. 5237 - 5240 (2007/10/02)
A highly regioselective reduction of propargylic acetates has been attained by using SmI2 and catalytic Pd(0) in the presence of 2,4-dimethyl-3-pentanol affording various types of allenes in high yields.
