110211-65-9

Upstream product

• 1595-53-5 4-methylpent-3-en-1-yne 
• 110211-64-8 1-[(1R,2S,4R,6R)-2-(tert-Butyl-dimethyl-silanyloxy)-6-hydroxy-4-methyl-cyclohexyl]-ethanone 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 110211-64-8 acetyl-2 methyl-5 TBDMSoxy-1 cyclohexanol-3 (1,3 trans) 
• 110211-62-6 dimethyl-4,9 oxa-7 aza-8 bicyclo <4,3,0> nonene-8 ol-2β 
• 7214-50-8 5-methylcyclohex-2-en-1-one 
• 110211-62-6 dimethyl-4,9 oxa-7 aza-8 bicyclo <4,3,0> nonene-8 ol-2α 
• 124578-35-4 acetyl-2 methyl-5 cyclohexanediol-1,3 (cis) 
• 110211-61-5 dimethyl-4,9 oxa-7 aza-8 bicyclo-<4,3,0> nonene-8 one-2 
• 110211-63-7 acetyl-2 methyl-5 cyclohexanediol-1,3 (trans) 

Downstream Products

• 110211-67-1 Acetic acid (R)-1-[(1S,2S,4S,6S)-2-(tert-butyl-dimethyl-silanyloxy)-4-methyl-6-(2-trimethylsilanyl-ethoxymethoxy)-cyclohexyl]-1,5-dimethyl-hex-4-en-2-ynyl ester 
• 110211-74-0 (3S,3aS,6R,7aR)-3,6-Dimethyl-2-[3-methyl-but-2-en-(Z)-ylidene]-5-phenylselanyl-3-triethylsilanyloxy-hexahydro-benzofuran-4-one 
• 110211-68-2 (R)-2-[(1S,2S,4S,6S)-2-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-6-(2-trimethylsilanyl-ethoxymethoxy)-cyclohexyl]-6-methyl-hept-5-en-3-yn-2-ol 
• 110211-74-0 phenylselenyl-5 TESoxy-3 (+/-) dihydrobisabolangelone (syn) 
• 110211-74-0 phenylselenyl-5 TESoxy-3 (+/-) dihydrobisabolangelone (anti) 
• 30557-81-4 (+/-) bisabolangelone 
• 124456-72-0 acetoxy-3 methyl-5 (methyl-6 hydroxy-2 heptene-5 yne-3 yl)-2 TBDMSoxy-1 cyclohexane (1,3 trans) 
• 110211-66-0 Acetic acid (S)-1-[(1R,2R,4R,6R)-2-(tert-butyl-dimethyl-silanyloxy)-6-hydroxy-4-methyl-cyclohexyl]-1,5-dimethyl-hex-4-en-2-ynyl ester 

Relevant academic research and scientific papers

SYNTHESE TOTALE DE LA (+/-) BISABOLANGELONE (1)

Bisabolangelone is a sesquiterpenoid well known for its strong antifeeding properties against phytophagous insects.In this communication, we describe the total synthesis of the target molecule, following a model study, which shows the possibilities to cyc

TOTAL SYNTHESIS OF (+/-)-BISABOLANGELONE

The total synthesis of the sesquiterpenoid (+/-) bisabolangelone 21 is described.The key step utilizes the heterocyclic five membered ring formation by cyclisation of a γ-acetylenic alcohol with the formation of an exocyclic conjugated enol ether in high