110224-52-7Relevant academic research and scientific papers
Template-Controlled Oligomerization Support Studies. Template Synthesis and Functionalization
Feldman, Ken S.,Bobo, John S.,Ensel, Susan M.,Lee, Yoon B.,Weinreb, Paul H.
, p. 474 - 481 (2007/10/02)
The rigid organic template 8 can be rapidly assembled via double Diels-Alder cycloaddition of methyl 9-anthracenecarboxylate (7) and trans-anti-trans-norbornadien trimer 5.Subsequent manipulation leads to differentially functionalized templates capable of mediating the oligoselective polymerization of acrylate monomers.Lactonization studies with template diol 10 provide a useful measure of the "effective molecular size" of the template.
