110230-71-2Relevant academic research and scientific papers
Enzymes in Organic Synthesis: Remarkable Influence of a ? System on the Enantioselectivity in PPL Catalysed Monohydrolysis of 2-Substituted 1,3-Diacetoxypropanes.
Guanti, Giuseppe,Banfi, Luca,Narisano, Enrica
, p. 721 - 724 (2007/10/02)
The results of PPL catalysed monohydrolysis of a series of 2-substituted-1,3-diacetoxypropanes showed that alkinyl and (E) alkenyl substituents led to improvement of yield and enantioselectivity, compared to their saturated analogues.On the contrary, (Z) alkenyl substituents provoked a net reversal of asymmetric induction.
