110296-07-6Relevant academic research and scientific papers
Magnetite (Fe3O4) nanoparticles: An efficient and recoverable catalyst for the synthesis of alkynyl chalcogenides (selenides and tellurides) from terminal acetylenes and diorganyl dichalcogenides
Godoi, Marcelo,Liz, Daiane G.,Ricardo, Eduardo W.,Rocha, Manuela S.T.,Azeredo, Juliano B.,Braga, Antonio L.
, p. 3349 - 3354 (2014/05/06)
We present herein a new and efficient methodology for the synthesis of alkynyl chalcogenides from terminal acetylenes and diorganyl dichalcogenides, catalyzed by Fe3O4 nanoparticles. This new approach provided the desired products in good to excellent yields. Moreover, the catalyst was easily recoverable using an external magnet and reused for further experiments without loss of catalytic activity.
An efficient synthesis of alkynyl selenides and tellurides from terminal acetylenes and diorganyl diselenides or ditellurides catalyzed by recyclable copper oxide nanopowder
Godoi, Marcelo,Ricardo, Eduardo W.,Frizon, Tiago E.,Rocha, Manuela S. T.,Braga, Antonio Luiz,Singh, Devender,Paixao, Marcio W.
, p. 10426 - 10430,5 (2012/12/12)
Herein, we report an efficient method for the synthesis of alkynyl selenides and tellurides from terminal alkynes and diorganyl diselenides or ditellurides using CuO nanopowder as a recyclable catalyst. This new methodology furnished the desired products in good to excellent yields. Furthermore, the catalyst was easily recovered and reused for further catalytic reactions without loss of activity.
An efficient and general procedure for the synthesis of alkynyl chalcogenides (selenides and tellurides) by alumina-supported Cu(II)-catalyzed reaction of alkynyl bromides and diphenyl dichalcogenides
Ahammed, Sabir,Bhadra, Sukalyan,Kundu, Debasish,Ranu, Brindaban C.,Sreedhar, Bojja
, p. 10542 - 10549,8 (2012/12/12)
Alumina (Al2O3) supported Cu(II) efficiently catalyzes the reaction of alkynyl bromides and diphenyl diselenides and ditellurides in presence of Zn dust or indium(I) bromide to provide the corresponding alkynyl selenides and tellurides. The reactions of a wide variety of substituted alkynyl bromides have been addressed. The zinc dust or InBr is required for the cleavage of diphenyl selenides/tellurides. The mechanism of the reaction is established. The yields of products are high and the catalyst is recycled.
An efficient and general procedure for the synthesis of alkynyl chalcogenides (selenides and tellurides) by alumina-supported Cu(II)-catalyzed reaction of alkynyl bromides and diphenyl dichalcogenides
Ahammed, Sabir,Bhadra, Sukalyan,Kundu, Debasish,Sreedhar, Bojja,Ranu, Brindaban C.
, p. 10542 - 10549 (2013/01/15)
Alumina (Al2O3) supported Cu(II) efficiently catalyzes the reaction of alkynyl bromides and diphenyl diselenides and ditellurides in presence of Zn dust or indium(I) bromide to provide the corresponding alkynyl selenides and tellurides. The reactions of a wide variety of substituted alkynyl bromides have been addressed. The zinc dust or InBr is required for the cleavage of diphenyl selenides/tellurides. The mechanism of the reaction is established. The yields of products are high and the catalyst is recycled.
Cesium hydroxide-catalyzed reaction of terminal alkynes with diarylditellurides to synthesize alkynyl tellurides
Zou, Kang Bing,Qiu, Ren Hua,Fang, Da Wei,Liu, Xin You,Xu, Xin Hua
, p. 2237 - 2242 (2008/09/21)
In the presence of a catalytic amount of cesium hydroxide under an air atmosphere, the reaction of diarylditellurides (1.0 mmol) with terminal alkynes (2.2 mmol) at room temperature exclusively give alkynyl tellurides in good yields. Copyright Taylor & Fr
