110320-03-1Relevant academic research and scientific papers
cine-Substitution in Halogenobenzenetricarbonylchromium Complexes
Rose-Munch, Francoise,Rose, Eric,Semra, Assia
, p. 1551 - 1552 (1986)
cine-Substitution of the chloro group of chlorobenzenetricarbonylchromium complexes by a carbon nucleophile has been observed.
Substitutions nucleophiles aromatiques SNAr cine et tele sur l'ortho, le meta et le para-chlorotoluenetricarbonylchrome
Rose-Munch, Francoise,Rose, Eric,Semra, Assia,Bois, Claudette
, p. 103 - 122 (2007/10/02)
The study of the regioselectivity of the addition of a nucleophile to chlorotoluenetricarbonylchromium complexes, under cine or tele SNAr conditions, indicated that stabilized carbanions added predominantly to the carbon eclipsed by a Cr-CO bond of the most stable conformer.The conformation of p-chlorotoluenetricarbonylchromium has been studied, in solution by 1H NMR and in the solid state by X-ray crystallography.
Substitutions nucleophiles aromatiques SNAr de fluorobenzenetricarbonylchrome
Rose-Munch, Francoise,Rose, Eric,Semra, Assia,Mignon, Laurent,Garcia-Oricain, Jesus,Knobler, Caroline
, p. 297 - 310 (2007/10/02)
cine and tele-nucleophilic aromatic substitutions occur upon treatment of fluorobenzenetricarbonylchromium complexes with a carbanion followed by acid treatment.
Substitution nucleophile aromatique cine en serie arenetricarbonylchrome
Rose-Munch, Francoise,Rose, Eric,Semra, Assia,Jeannin, Yves,Robert, Francis
, p. 53 - 64 (2007/10/02)
2-Lithio-2-phenyl-1,3-dithiane reacts with p-chlorotoluenetricarbonylchromium to give, after treatment with CF3CO2H, the sole cyclohexadiene isomer 1-methyl-4-chloro-5(2'-phenyl-1',3'-dithiane)-1,3-cyclohexadiene, which was characterized by X-ray crystall
