110347-76-7Relevant academic research and scientific papers
CHEMICAL AND ENZYMATIC TRIGGERING OF 1,2-DIOXETANES. 1: ARYL ESTERASE-CATALYZED CHEMILUMINESCENCE FROM A NAPHTYL ACETATE-SUBSTITUTED DIOXETANE
Schaap, A. Paul,Handley, Richard S.,Giri, Brij P.
, p. 935 - 938 (1987)
A thermally stable 1,2-dioxetane bearing a naphthyl acetate group is enzymatically cleaved in aqueous buffer to generate chemiluminescence at ambient temperature.
Synthesis of 3,3-diisopropyl-4-methoxy-4-(siloxy-2-naphthyl)-1,2- dioxetanes and their F--induced chemiluminescent decomposition
Watanabe, Nobuko,Kobayashi, Hisako,Azami, Mitsunori,Matsumoto, Masakatsu
, p. 6831 - 6840 (1999)
Six isomeric 3,3-diisopropyl-4-methoxy-4-(siloxy-2-naphthyl)-1,2- dioxetanes (3) were synthesized and their F--induced chemiluminescent decomposition were examined in DMSO. The 'odd/even' relationship in Φ(CL) holds for all the dioxetanes (3). On the other hand, the 'odd/even' relationship in emission half-lives t(1/2) is observed for dioxetanes (3c- 3f) with a trigger on the ring B but not for dioxetanes (3a and 3b) with a trigger on the ring A.
