1103517-15-2Relevant academic research and scientific papers
Diastereoselective Synthesis of Highly Substituted Tetrahydrofurans by Pd-Catalyzed Tandem Oxidative Cyclization-Redox Relay Reactions Controlled by Intramolecular Hydrogen Bonding
Brooks, Joshua L.,Xu, Liping,Wiest, Olaf,Tan, Derek S.
, p. 57 - 75 (2017)
Palladium-catalyzed oxidative cyclization of alkenols provides a convenient entry into cyclic ethers but typically proceeds with little or no diastereoselectivity for cyclization of trisubstituted olefins to form tetrahydrofurans due to the similar energi
Initiating radical cyclizations by H{radical dot} transfer from transition metals
Hartung, John,Pulling, Mary E.,Smith, Deborah M.,Yang, David X.,Norton, Jack R.
experimental part, p. 11822 - 11830 (2009/04/11)
CpCr(CO)3H and HV(CO)4(P-P) (where P-P is a chelating diphosphine) can be used to initiate radical cyclizations by transferring H{radical dot} to activated terminal olefins. CpCr(CO)3H can catalyze reductive cyclizations,
