110352-95-9Relevant academic research and scientific papers
PHOSPHINSUBSTITUIERTE CHELATLIGANDEN XIX. DIASTEREOSELEKTIVE KOMPLEXBILDUNG MIT CHIRALEN PHOSPHINOTHIOFORMAMIDEN
Kunze, U.,Jawad, H.,Burghardt, R.,Tittmann, R.,Kruppa, V.
, p. C30 - C34 (2007/10/02)
We suggest three ways for the synthesis of chiral phosphinothiofprmamide ligands with an asymmetric centre at carbon or phosphorus.The stereoselectivity of the complex formation with CpM(CO)3Cl (M = Mo, W) is controlled by thermodynamic and kinetic factor
