110374-96-4

Basic information

• Product Name: C₁₁H₁₀⁽²⁾H₂O₂
• Synonyms: C₁₁H₁₀⁽²⁾H₂O₂
• CAS NO: 110374-96-4
• Molecular Weight: 178.199
• Mol File: 110374-96-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₁H₁₀⁽²⁾H₂O₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₁H₁₀⁽²⁾H₂O₂(110374-96-4)
• EPA Substance Registry System: C₁₁H₁₀⁽²⁾H₂O₂(110374-96-4)

Safety Data

• Hazardous Substances Data: 110374-96-4(Hazardous Substances Data)

Upstream product

• 10475-51-1 1,1-dideuterio-2-propenol 
• 103-80-0 phenylacetyl chloride 

Downstream Products

• 14815-73-7 methyl allylphenylacetate 
• 67031-09-8 methyl 2-(4-chlorophenyl)pent-4-enoate 
• 1257847-70-3 C₁₂H₁₂⁽²⁾H₂O₂ 
• 1257847-69-0 C₁₂H₁₂⁽²⁾H₂O₂ 
• 1257847-68-9 C₁₂H₁₁⁽²⁾H₂ClO₂ 
• 1257847-67-8 C₁₂H₁₁⁽²⁾H₂ClO₂ 

Relevant articles and documents

Sigmatropic Rearrangements of Deprotonated Allyl Phenylacetates in the Gas Phase

The ion C6H5C-HCO2CH2CH=CH2 undergoes competitive losses of C3H5OH and CO2 on collisional activation.The loss of C3H5OH proceeds through ion complex -(C6H5CH=C=O)> yielding C6H5CCO- and C3H5OH.This reaction occurs without prior ester equilibration C6H5C-HC(O)O*C3H5C6H5C-HC(O*)OC3H5.The elimination of CO2 follows rearrangement C6H5C-HCO2C3H5->C6H5(C3H5)CHCO2-.The rearrangement occurs through both six- and four-center transition states with the six-center (Claisen) rearrangement predominating.