110397-50-7Relevant academic research and scientific papers
A new dirhodium catalyst with hemilabile tropolonato ligands for C-H bond functionalization
Thrun, Frauke,Butschke, Burkhard,Graening, Timm
, p. 4854 - 4858 (2012)
Don't hold on too tightly! In a new dirhodium catalyst for C-H functionalization reactions, two tropolonato ligands are introduced as hemilabile chelating ligands (see scheme). Only two bridges hold the Rh-Rh core together. The tropolonato ligands can liberate a binding site in the equatorial coordination sphere of the catalyst. This opens a doorway to new mechanistic channels in C-H functionalization. Copyright
Synthesis of 2-Indanones by Intramolecular Insertion of α-Diazoketones
Nakatani, Kazuhiko
, p. 165 - 166 (2007/10/02)
The reaction of α-diazoketones from phenylacetic acid derivatives affords 2-indanones in good yield.Insertion into the aromatic C-H bond was found to be favored over insertion into an aliphatic one.
