110398-00-0Relevant academic research and scientific papers
Darstellung von Arylhalogenboranen
Haubold, Wolfgang,Herdtle, Joerg,Gollinger, Walter,Einholz, Wolfgang
, p. 1 - 8 (2007/10/02)
In a ligand-exchange reaction between aryltrimethylsilanes, (ArSiMe3) and halogenboranes, (BX3 or ArBX2), arylhalogenboranes (ArBX2, ArAr'BX or Ar2BX) and halogentrimethylsilane are formed.This transfer of substituted aromatic groups from a silicon to a boron atom is an efficient synthetic pathway for the preparation of the corresponding arylhalogenboranes and diarylhalogenboranes with different aryl groups.Physical properties and spectroscopical data of the new arylhalogenboranes are given.
