110416-15-4

Upstream product

• 110360-74-2 (E)-(S)-4-((1S,3S,4S,6R)-7-Acetoxy-1,4,6-trimethyl-2,5-dioxa-bicyclo[2.2.1]hept-3-yl)-4-hydroxy-pent-2-enoic acid ethyl ester 
• 96727-27-4 4-Methoxy-5-methyl-6-[(E)-3-(triphenyl-λ⁵-phosphanylidene)-propenyl]-pyran-2-one 
• 110360-76-4 (E)-(S)-4-Hydroxy-4-((1R,3S,4R,6R)-7-hydroxy-1,4,6-trimethyl-2,5-dioxa-bicyclo[2.2.1]hept-3-yl)-pent-2-enal 

Relevant academic research and scientific papers

Total Synthese of Citreoviridinol and Neocitreoviridinol

Both citreoviridinol and neocitreoviridinol, metabolites of Penicillium citreo-viride B., have been synthesized from the known synthetic intermediate of citreoviridin, in regio- and stereoselective manner.

ISOLATION AND STEREOSTRUCTURES OF NEOCITREOVIRIDINOL AND EPINEOCITREOVIRIDINOL

Both neocitreoviridinol and epineocitreoviridinol with a 2,5-dioxabicycloheptane ring have been isolated as new metabolites of Penicilliumcitreo-viride B., and their stereostructures have also been elucidated on the basis of their spectral data coupled with molecular mechanics calculations.In addition, a promising synthetic intermediate for neocitreoviridinol has been made.