110458-19-0Relevant academic research and scientific papers
Conformational Preference in 1,3-Dithianes Containing 2-Phosphoryl, -(thiophosphoryl), and -(selenophosphoryl) groups. Chemical and Crystallographic Implications of the Nature of the Anomeric Effect
Mikolajczyk, Marian,Graczyk, Piotr P.,Wieczorek, Michal W.
, p. 1672 - 1693 (2007/10/02)
The operation of anomeric effect in all the title compounds studied was found.The magnitude of the anomeric effect was found to be larger than 10 kJ/mol.Crystallographic, spectroscopic, and thermodynamic data suggest that nS-?*C
Conformational Preference of the Diphenylthiophosphinoyl Group in Cyclohexane and in the 1,3-Dithian-2-yl Ring
Juaristi, Eusebio,Lopez-Nunez, Norma A.,Valenzuela, Bertha A.,Valle, Lucia,Toscano, Ruben A.,Soriano-Garcia, Manuel
, p. 5184 - 5189 (2007/10/02)
The conformational energy (A value) of the diphenylthiophosphinoyl group in cyclohexane was determined from the incorporation of 13C NMR data of mobile cis-4-(diphenylthiophosphinoyl)-1-phenylcyclohexane (4) and conformationally fixed cis- (5) and trans-4
