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110479-58-8

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  • Tin(II) 2,3-naphthalocyanine CAS NO.110479-58-8

    Cas No: 110479-58-8

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110479-58-8 Usage

Uses

Used in the synthesis of naphthalocyanine based nano-crystalline thin films which show near IR absorption and high extinction coefficient inorganic thin film devices.

General Description

Tin (II) 2,3-naphthalocyanine is widely used in organic photodiodes and solar cells since it exhibits very strong absorption in the infrared region (IR).This increases the power conversion efficiencies (PCE) of organic photovoltaic (OPV) cells since it absorbs light in the near infrared and infra-red portions of the electromagnetic spectrum which accounts for 50% of the solar photon flux.

Check Digit Verification of cas no

The CAS Registry Mumber 110479-58-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,0,4,7 and 9 respectively; the second part has 2 digits, 5 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 110479-58:
(8*1)+(7*1)+(6*0)+(5*4)+(4*7)+(3*9)+(2*5)+(1*8)=108
108 % 10 = 8
So 110479-58-8 is a valid CAS Registry Number.
InChI:InChI=1/C48H24N8.Sn.2H/c1-2-10-26-18-34-33(17-25(26)9-1)41-49-42(34)54-44-37-21-29-13-5-6-14-30(29)22-38(37)46(51-44)56-48-40-24-32-16-8-7-15-31(32)23-39(40)47(52-48)55-45-36-20-28-12-4-3-11-27(28)19-35(36)43(50-45)53-41;;;/h1-24H;;;/q-2;+2;;/rC48H24N8.H2Sn/c1-2-10-26-18-34-33(17-25(26)9-1)41-49-42(34)54-44-37-21-29-13-5-6-14-30(29)22-38(37)46(51-44)56-48-40-24-32-16-8-7-15-31(32)23-39(40)47(52-48)55-45-36-20-28-12-4-3-11-27(28)19-35(36)43(50-45)53-41;/h1-24H;1H2/q-2;+2

110479-58-8 Well-known Company Product Price

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  • Aldrich

  • (764949)  Tin(II)2,3-naphthalocyanine  

  • 110479-58-8

  • 764949-500MG

  • 1,451.97CNY

  • Detail

110479-58-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name tin naphthalocyanine

1.2 Other means of identification

Product number -
Other names tin-naphthalocyanine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:110479-58-8 SDS

110479-58-8Downstream Products

110479-58-8Relevant articles and documents

Synthesis and photochemical properties of aluminum, gallium, silicon, and tin naphthalocyanines

Ford, William E.,Rodgers, Michael A. J.,Schechtman, Lee A.,Sounik, James R.,Rihter, Boris D.,Kenney, Malcolm E.

, p. 3371 - 3377 (2008/10/08)

The synthesis and characterization of 30 Al, Ga, Si, and Sn naphthalocyanines relevant to the search for improved photodynamic therapy agents are reported. The compounds that have been studied are AlNcCl, AlNcOH, AlNcOSi-(n-C6H13)3, (AlNcF)n, GaNcCl, GaNcOH, GaNcOH·2H2O, GaNcOSin-C6H13)3, (GaNcF)n, SiNc(O-n-C8H17)2, SiNc[(OCH2CH2)~17OCH3] 2, SiNc[(OCH2CH2)~43OCH3] 2, SiNc[4-OCH2CH2)~26OC6H 4C(CH3)2CH2C(CH3) 3]2, SiNc[4-OC6H4CO(OCH2CH2) 3OCH3]2, SiNc[OSi(n-C4H9)2(n-C18H 37)]2, SiNc[OSi(i-C4H9)2(n-C18H 37)]2, SiNc[OSi(CH3)2(CH2)10COOCH 3]2, SiNc(2/3-Cl)4Cl2, SiNc(2/3-Cl)4(O-n-C8H17)2, SiNc(2/3-Cl)4[OSi(n-C6H13)3] 2, SiNc[2/3-Cl)4(OH)2, SiNc(2/3-Br)4Cl2, SiNc(2/3-Br)4(O-n-C8H17)2, SiNc(2/3-Br)4[OSi(n-C6H13)3] 2, SiNc(2/3-Br)4(OH)2, SnNcCl2, SnNc, SnNcI2, SnNc(OH)2, and SnNc[OSi(n-C6H13)3]2. For nine of these compounds and for an additional compound, SiNc[OSi(n-C6H13)3]2, one or more of the following photoproperties have been determined: λQ, the Q(0,0)-band absorption maximum; ΦT, the triplet-state quantum yield or ΦT′, an approximation of ΦT; Δ∈T the triplet-minus-ground-state extinction coefficient difference at 590 nm; τT, the triplet-state lifetime in the absence of O2; and kox, the bimolecular rate constant for the quenching of the triplet state by O2. The values obtained show that λQ is essentially independent of the kinds of atoms in the 2 and 3 positions of the macrocycle and that ΦT is moderately and directly dependent on the atomic numbers of the atoms in the center and the 2 and 3 positions of the ring. In the case of the silicon naphthalocyanines, they show in addition that λQ, ΦT′, and τT are moderately dependent on the type of axial ligand present.

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