110509-87-0Relevant articles and documents
Formation and Reactions of Olefins with Vicinal Silyl and Stannyl Substituents
Mitchell, T. N.,Wickenkamp, R.,Amamria, A.,Dicke, R.,Schneider, U.
, p. 4868 - 4874 (2007/10/02)
The silicon-tin bond in Me3SiSnR3 (R=Me, n-Bu) adds regio- and stereospecifically to 1-alkynes and also to a limited number of nonterminal alkynes when Pd(PPh3)4 is added as a catalyst.The use of the (Z)-silylstannylalkenes thus formed in synthesis either