110522-35-5Relevant academic research and scientific papers
A Novel Aspect in Chlorination of D-Glucal Derivatives. Important Roles of the 4,6-O-Benzylidene Group and Substituent at C-3 in the Selective Formation of β-D-Manno and β-D-Arabino Isomers
Sakakibara, Tohru,Yatabe, Takumi,Yoshino, Kohji,Ishido, Yoshiharu
, p. 7 - 10 (2007/10/02)
In contrast with the precedent reports described in peracetyl- and perbenzyl-D-glucal, chlorination of 3-O-acetyl- and 3-deoxy-4,6-O-benzylidene-D-glucal in carbon tetrachloride predominantly occurred from the β-side to give the β-D-manno and β-D-arabino
