110550-20-4Relevant academic research and scientific papers
AN ENANTIOCONVERGENT ROUTE TO CARBOCYCLIC NUCLEOSIDES (-)-ARISTEROMYCIN AND (-)-NEPLANOCIN A VIA THE ASYMMETRIC DIELS-ALDER REACTION
Arai, Yoshitsugu,Hayashi, Yoshikazu,Yamamoto, Masatoshi,Takayema, Hiromitsu,Koizumi, Toru
, p. 3133 - 3140 (2007/10/02)
The asymmetric Diels-Alder reaction of (SS)-menthyl-3-(2-pyridylsulphinyl)acrylate (4) with cyclopentadiene gave almost a pure single diastereoisomeric cycloadduct.The cycloadduct was then converted into the central intermediate (+)-(3) which w
A New Route to (-)-Aristeromycin and (-)-Neplanocin A via the Asymmetric Diels-Alder Cycloaddition
Arai, Yoshitsugu,Hayashi, Yoshikazu,Yamamoto, Masatoshi,Takayama, Hiromitsu,Koizumi, Toru
, p. 185 - 186 (2007/10/02)
An enantioselective synthesis of a central intermediate in the synthesis of (-)-aristeromycin and (-)-neplanocin A via the asymmetric Diels-Alder reaction of menthyl (S)s-3-(2-pyridylsulfinyl)propenoate with cyclopentadiene, is described.
