110560-40-2

Upstream product

• 110560-37-7 (2S,3S)-3-((Z)-(S)-3-Hydroxy-5-phenyl-pent-1-enyl)-2-[2-(3-methoxy-bicyclo[4.2.0]octa-1,3,5-trien-7-yl)-ethyl]-2-methyl-cyclopentanone 
• 110560-34-4 2-[2-(3-Methoxy-bicyclo[4.2.0]octa-1,3,5-trien-7-yl)-ethyl]-cyclopent-2-enone 

Downstream Products

• 110560-42-4 (7S,8R,9S,13S,14S)-3-Methoxy-13-methyl-7-(3-phenyl-propionyl)-6,7,8,9,11,12,13,14,15,16-decahydro-cyclopenta[a]phenanthren-17-one 

Relevant academic research and scientific papers

Enantioselective approach to the steroid skeleton by conjugate addition of alkenylcopper-phosphine complexes. Total syntheses of estrone methyl ether and its 7-alkylated derivative

Enantioselective syntheses of estrone methyl ether and its 7-alkylated derivative by the conjugate addition of alkenylcopper-phosphine complexes and discussions for the diastereoselectivity in the intramolecular Diels-Alder reaction of the o-quinodimethane derivative on the basis of MM2 transition structure models are presented.