110569-30-7

Basic information

• Product Name: (1R,2R,3R,4R)-2,3-Dicyano-1,4-diphenyl-1,2,3,4-tetrahydro-naphthalene-2,3-dicarboxylic acid dimethyl ester
• CAS NO: 110569-30-7
• Molecular Weight: 450.494
• Mol File: 110569-30-7.mol

Chemical Properties

• CAS DataBase Reference: (1R,2R,3R,4R)-2,3-Dicyano-1,4-diphenyl-1,2,3,4-tetrahydro-naphthalene-2,3-dicarboxylic acid dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2R,3R,4R)-2,3-Dicyano-1,4-diphenyl-1,2,3,4-tetrahydro-naphthalene-2,3-dicarboxylic acid dimethyl ester(110569-30-7)
• EPA Substance Registry System: (1R,2R,3R,4R)-2,3-Dicyano-1,4-diphenyl-1,2,3,4-tetrahydro-naphthalene-2,3-dicarboxylic acid dimethyl ester(110569-30-7)

Safety Data

• Hazardous Substances Data: 110569-30-7(Hazardous Substances Data)

Upstream product

• 35234-87-8 dimethyl 2,3-dicyanofumarate 
• 6894-86-6 cis-1,2-diphenyl-1,2-dihydrobenzocyclobutene 

Relevant articles and documents

Electron-Transfer Photochemistry of Benzocyclobutenes. - Stereospecific Electrocyclic Reactions of their Cation Radicals

The facile activation of cis- and trans-1,2-diphenylbenzocyclobutene (DBC) either by charge-transfer irradiation of the electron donor-acceptor complex with tetracyanoethylene or by chloranil photosensitization leads to a series of rapid cycloadditions.The role of the cation radical DBC(+*) as the reactive intermediate which undergoes a stereospecific, conrotatory cycloreversion is delineated, especially with regard to "contact" and "solvent-separated" ion pairs.Such cycloadditions induced by electron transfer are discussed in the contex of the thermal valence tautomerization of DBC previously established by Huisgen, Quinkert, and co-workers.