110577-12-3

Upstream product

• 146440-99-5 1-phenyl-2-bromo-3,4-dimethylphosphole 
• 157890-35-2 2,5-Dibromo-3,4-dimethyl-1-phenyl-1H-phosphole 
• 30540-36-4 3,4-dimethyl-1-phenylphosphole 
• 110577-13-4 1,1'-diphenyl-3,3',4,4'-tetramethyl-2,2'-biphosphole-P,P'-disulfide 
• 74395-12-3 1-phenyl-3,4-dimethylphosphole oxide 
• 157890-32-9 2-Bromo-3,4-dimethyl-1-phenyl-phosphole 1-oxide 
• 146440-97-3 (1S,2S,5R)-2,5-Dibromo-3,4-dimethyl-1-phenyl-2,5-dihydro-phosphole 1-sulfide 
• 146440-96-2 1-phenyl-2,5-dibromo-3,4-dimethyl-2,5-dihydrophosphole oxide 
• 146440-98-4 2-Bromo-3,4-dimethyl-1-phenyl-phosphole 1-sulfide 
• 157890-33-0 2,2,5-Tribromo-3,4-dimethyl-1-phenyl-2,5-dihydro-phosphole 1-oxide 
• 157890-34-1 2,5-Dibromo-3,4-dimethyl-1-phenyl-phosphole 1-oxide 

Downstream Products

• 110543-32-3 (η¹-P,η¹-P'-1,1'-diphenyl-3,3',4,4'-tetramethyl-2,2'-biphosphole)octacarbonyldimanganese 
• 110577-13-4 1,1'-diphenyl-3,3',4,4'-tetramethyl-2,2'-biphosphole-P,P'-disulfide 
• 187547-33-7 (1R,1'S)-3,4,3',4'-Tetramethyl-1,1'-diphenyl-1H,1'H-[2,2']biphospholyl 
• 219566-13-9 trans-meso-[Ru(trifluoroacetate)2(1,1'-diphenyl-3,3',4,4'-tetramethyl-2,2'-biphosphole)2] 
• 375371-07-6 [Rh(1,1'-diphenyl-3,3',4,4'-tetramethyl-2,2'-biphosphole)]⁽¹⁺⁾BF₄^(1-) 
• 375372-17-1 (RR)-[Ir(1,1'-diphenyl-3,3',4,4'-tetramethyl-2,2'-biphosphole)(1,5-cyclooctadiene)]⁽¹⁺⁾BF₄^(1-) 
• 375371-41-8 (SS)-[Ir(1,1'-diphenyl-3,3',4,4'-tetramethyl-2,2'-biphosphole)(1,5-cyclooctadiene)]⁽¹⁺⁾BF₄^(1-) 
• 374824-07-4 [Rh(1,1'-diphenyl-3,3',4,4'-tetramethyl-2,2'-biphosphole)]⁽¹⁺⁾Cl^(1-) 
• 374824-07-4 bis(1,1'-diphenyl-3,3',4,4'-tetramethyl-2,2'-biphosphole)rhidium(I) chloride 
• 346406-47-1 dichloro(1,1'-diphenyl-3,3',4,4'-tetramethyl-2,2'-biphosphole)palladium(II) 
• 187327-04-4 dichloro(1,1'-diphenyl-3,3',4,4'-tetramethyl-2,2'-biphosphole)platinum(II) 

Relevant academic research and scientific papers

X-Ray characterization of enantiomerically pure 1,1′-diphenyl-3,3′,4,4′tetramethyl-2,2′-biphosphole: A ligand with axial and central chirality

The stereochemical analysis and characterization of diastereoisomers of 1,1′-diphenyl-3,3′,4,4′-tetramethyl-2,2′-biphosphole having axial and central chirality reveal the potential interest of this ligand for asymmetric catalysis.

Preparation and synthetic uses of a 2-lithiophosphole

1-Phenyl-2-bromo-3,4-dimethylphosphole was prepared from 1-phenyl-3,4-dimethylphosphole via a sequence involving oxidation at phosphorus, bromination and dehydrobromination of the dienic system, and finally, PV to PIII conversion by

SYNTHESIS AND SOME REACTIONS OF A 2,2'-BIPHOSPHOLYL

1,1'-Diphenyl-3,3',4,4'-tetramethyl-2,2',5,5'-tetrahydro-2,2'-biphosphole obtained by reductive dimerization of the appropriate phosphole has been converted into the corresponding 2,2'-biphosphole by P-bromination followed by dehydrobromination of the resulting P,P'-tetrabromo compound with α-picoline.This 2,2'-biphosphole gives two isomeric P-sulfides upon reaction with sulfur, and a Mo(CO)4 chelate upon reaction with Mo(CO)6.Cleavage of the two P-phenyl bonds by lithium in THF yields the corresponding biphospholyl anion, which is converted into a mixture of two isomeric bis(η5,η5-2,2'-diphosphafulvalene)diirons by treatment with FeCl2.The reaction of Mn2(CO)10 in boiling xylene affords a mixture of three complexes, including a (η5,η5-2,2'-diphosphafulvalene)hexacarbonyldimanganese produced by thermal cleavage of the two P-Ph bonds.Under CO pressure there is a P --> C shift of the two phenyl groups, leading to formation of (η5,η5-3,3'-diphenyl-2,2'-diphosphafulvalene)hexacarbonyldimanganese.