110596-16-2

Basic information

• Product Name: ethyl (E)-3-<<(benzylidene)methyl>iminoxy>-(E)-2-(methoxyimino)propionate
• CAS NO: 110596-16-2
• Molecular Weight: 278.308
• Mol File: 110596-16-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl (E)-3-<<(benzylidene)methyl>iminoxy>-(E)-2-(methoxyimino)propionate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (E)-3-<<(benzylidene)methyl>iminoxy>-(E)-2-(methoxyimino)propionate(110596-16-2)
• EPA Substance Registry System: ethyl (E)-3-<<(benzylidene)methyl>iminoxy>-(E)-2-(methoxyimino)propionate(110596-16-2)

Safety Data

• Hazardous Substances Data: 110596-16-2(Hazardous Substances Data)

Upstream product

• 70-23-5 ethyl Bromopyruvate 
• 10341-75-0 (E)-1-phenylethanone oxime 
• 110596-14-0 ethyl 3-bromo-(Z)-2-(methoxyimino)propionate 

Downstream Products

• 110596-24-2 (E)-3-<<(benzylidene)methyl>iminoxy>-(E)-2-(methoxyimino)propionic acid 

Relevant articles and documents

SYNTHESIS OF 3-IMINOXY-(E)-2-METHOXYIMINOPROPIONIC ACID DERIVATIVES AND X-RAY CRYSTALLOGRAPHIC ANALYSIS OF ETHYL (E)-3--(E)-2-(METHOXYIMINO)PROPIONATE

Reaction of ethyl α-bromopyruvate, 7, with methoxyamine hydrochloride stereoselectively yielded ethyl 3-bromo-(Z)-2-methoxyiminopropionate, 8.The displacement of the bromine of 8 with the oximes 9 gave ethyl 3-iminoxy-(E)-2-methoxyiminopropionate derivatives 10 which were transformed into the corresponding free acids 4.The configuration around the double bond of the methoxyimino moiety was assigned on the basis of the X-ray crystallographic analysis of the ethyl ester of the acid 4d (10d).