110598-64-6

Upstream product

• 18407-42-6 (iodomethyl)methyldiphenylsilane 
• 114278-59-0 tris(4-methoxyphenyl)phosphonium methylide 

Downstream Products

• 110598-85-1 [(R)-1-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-allyloxy]-methyl-diphenyl-silane 
• 110598-85-1 [(R)-1-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-allyloxy]-methyl-diphenyl-silane 
• 110598-77-1 [(R)-1-((S)-1-Benzyloxy-ethyl)-allyloxy]-methyl-diphenyl-silane 
• 110598-77-1 [(R)-1-((R)-1-Benzyloxy-ethyl)-allyloxy]-methyl-diphenyl-silane 
• 114289-06-4 Methyl-{(R)-1-[(2S,3S)-3-methyl-3-(4-methyl-pent-3-enyl)-oxiranyl]-allyloxy}-diphenyl-silane 
• 114289-06-4 Methyl-{(S)-1-[(2S,3S)-3-methyl-3-(4-methyl-pent-3-enyl)-oxiranyl]-allyloxy}-diphenyl-silane 
• 114289-07-5 Methyl-[(S)-1-((2S,3R)-2-methyl-3-phenethyl-oxiranyl)-allyloxy]-diphenyl-silane 
• 114289-07-5 Methyl-[(R)-1-((2S,3R)-2-methyl-3-phenethyl-oxiranyl)-allyloxy]-diphenyl-silane 
• 114289-07-5 Methyl-[(S)-1-((2S,3S)-2-methyl-3-phenethyl-oxiranyl)-allyloxy]-diphenyl-silane 
• 114289-07-5 Methyl-[(R)-1-((2S,3S)-2-methyl-3-phenethyl-oxiranyl)-allyloxy]-diphenyl-silane 
• 110598-69-1 ((1R,2R)-2-Methoxy-4-phenyl-1-vinyl-butoxy)-methyl-diphenyl-silane 
• 110598-69-1 ((1R,2S)-2-Methoxy-4-phenyl-1-vinyl-butoxy)-methyl-diphenyl-silane 
• 110598-71-5 Acetic acid (1S,2R)-2-(methyl-diphenyl-silanyloxy)-1-phenethyl-but-3-enyl ester 
• 110598-71-5 Acetic acid (1R,2R)-2-(methyl-diphenyl-silanyloxy)-1-phenethyl-but-3-enyl ester 

Relevant academic research and scientific papers

HIGH DIASTEREOSELECTIVITY OBSERVED IN THE VINYLATION REACTION OF α,β-EPOXY ALDEHYDES WITH β-SILYLPHOSPHOROUS YLIDE

The high erythro diastereofacial selectivities were observed in the silyl group migrative vinylation of α,β-epoxy aldehydes substituted by an alkyl or silyl group at the β-position using 2-diphenylmethylsilylethylidene-tris(4-methoxyphenyl)phosphorane.

CARBONYL ADDITION REACTION BY MEANS OF β-SILYLPHOSPHOROUS YLIDE. ANTI-DIASTEREOSELECTIVE VINYLATION OF α-ALKOXY ALDEHYDES.

β-Silylphosphorous ylide 1c reacts with α-alkoxy aldehydes 2 to give exclusively vinylation product 3, with high anti-diastereoselectivity.